Toluene → 1-Ethyl-4-Methylbenzene

HRID 374724

反応式

HRID 374724 の反応式
[N+]([O-])([O-])=O.[Ca+2].[N+]([O-])([O-])=O.[C:10]1([CH3:16])[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=1.[CH3:17][C:18]1[CH:19]=[CH:20][C:21]([CH3:24])=[CH:22][CH:23]=1>ClCCl>[CH2:16]([C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=1)[CH3:17].[CH2:17]([C:18]1[CH:23]=[CH:22][C:21]([CH3:24])=[CH:20][CH:19]=1)[CH3:10]

参加物

6

反応物 3

HCID 1140TolueneHCID 7809P-XyleneHCID 24963Calcium nitrate

生成物 2

HCID 7500Ethylbenzene収率 86%HCID 121601-Ethyl-4-Methylbenzene収率 89%

試薬・触媒・溶媒 1

HCID 6344Dichloromethane溶媒

実験手順

Pilot-scale treatments also support the laboratory incubations. The addition of calcium nitrate to the sediments of the Dofasco Boatslip in 1992 resulted in the biodegradation of several organic compounds (mean of three samples, reductions as follows; toluene 80%, ethylbenzene 86%, m/p-xylene 76%, 3/4-ethyltoluene 89%, and dichloromethane 65%) (FIG. 29). These relatively rapid biodegradation rates are similar to those reported in laboratory studies where nitrate was added to enhance biodegradation (Hutchins 1991).

出典と根拠

ORDレコード
ord-815d51115fc74d2f826bc2eee2c15095
出典データセット
uspto-grants-1996_01
特許番号
US05481815

関連ノート

読み込み中…