関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Ethanol | HCID 702 | — |
| 反応物 | Toluene | HCID 1140 | — |
| 反応物 | Glyoxal | HCID 7860 | — |
| 反応物 | Oleylamine | HCID 5356789 | — |
| 反応物 | HCID 178424185 | HCID 178424185 | — |
| 生成物 | HCID 178424361 | HCID 178424361 | — |
反応手順
Approximately 80 grams (0.6 mole) tolyltriazole (Sherwin Williams Co.), 167 grams (0.6 mole) oleyl amine (Armak-O, Armak Chemical Co.), 100 ml ethanol, and 100 ml toluene were charged to a 1 liter flask equipped with an agitator, Dean-Stark apparatus and dropping funnel. This mixture was stirred to a homogeneous mixture. Glyoxal (43.5 grams, 0.3 mole, 40% in water) was added dropwise and then stirred at room temperature for 12 hours. Water was then azeotropically removed by heating to 115° C. The dark brown product (261 grams) was isolated by filtration and removal of solvent under reduced pressure.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US05482521 |
|---|
| 出典データセット | uspto-grants-1996_01 |
|---|
| ORD ID | ord-b79046aa2f104887a01733bb89c6ad50 |
|---|
| 出典メモ | uspto-grants-1996_01 |
|---|
