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2-Ethylhexanal → 5-Amino-5-hydroxymethyl-2-(3-heptyl)-1,3-dioxane
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 2-Ethylhexanal | HCID 31241 | — |
| 反応物 | Tris(hydroxymethyl)nitromethane | HCID 31337 | — |
| 生成物 | 5-Amino-5-hydroxymethyl-2-(3-heptyl)-1,3-dioxane | HCID 18996049 | 95.1% |
反応手順
Procedure of Example 2 was repeated with 6.41 g of 2-ethylhexanal and 7.56 g of 2-(hydroxymethyl)-2-nitro-1,3-propanediol to give 11 g of 5-nitro-5-hydroxymethyl-1,3-dioxane derivative, which was reduced and distilled at 175°-178° C. to give 8.7 g of the product.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05482965 |
| 出典データセット | uspto-grants-1996_01 |
| ORD ID | ord-3a82a3418c454d79b570a00b1fb4f332 |
| 出典メモ | uspto-grants-1996_01 |