化工社化工社 化学情報印刷レポート · 研究参考用
5-Azidomethyl-2-carboxyethylfuran → 5-Aminomethyl-2-carboxyethylfuran
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 5-Azidomethyl-2-carboxyethylfuran | HCID 18993306 | — |
| 触媒 | Nickel | HCID 935 | — |
| 溶媒 | Ethanol | HCID 702 | — |
| 生成物 | 5-Aminomethyl-2-carboxyethylfuran | HCID 18993174 | 98.5% |
反応手順
Treatment of a solution in ethanol (50 mL) at ambient temperature of 5-azidomethyl-2-carboxyethylfuran (585 mg, 3.00 mmol), prepared as in step 3, with Raney nickel 2800 and 4 atmospheres of H2 for 24 hours, followed by filtration of the reaction mixture and concentration in vacuo gave 5-aminomethyl-2-carboxyethylfuran (0.50 g) as a yellow oil.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05486525 |
| 出典データセット | uspto-grants-1996_01 |
| ORD ID | ord-6f66f430e4d846f59b020b67e134241f |
| 出典メモ | uspto-grants-1996_01 |