化工社化工社 化学情報印刷レポート · 研究参考用
1-Hexene → Allylhexyldichlorosilane
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 1-Hexene | HCID 11597 | — |
| 反応物 | Dichloro(prop-2-enyl)silane | HCID 77536 | — |
| 触媒 | Chloroplatinic acid | HCID 61859 | — |
| 溶媒 | Isopropanol | HCID 3776 | — |
| 生成物 | Allylhexyldichlorosilane | HCID 11218382 | 79,283.797% |
反応手順
Using the same apparatus and procedure described in EXAMPLE 1, 59.7 g (0.71 mol) of 1-hexene and 80 μl of 1% chloroplatinic acid in isopropanol were added to the flask. Through the dropping funnel was added dropwise 10 g (0.07 mmol) of allyldichlorosilane for 30 rain while refluxing. After confirming by gas chromatography to complete the reaction, vacuum distillation (48°-50° C./0.5 torr) gave 12.5 g (79.3%) of 4,4-dichloro-4-sila-1 -decene.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05420323 |
| 出典データセット | uspto-grants-1995_05 |
| ORD ID | ord-5969ae89b2384cd0b55903e6f6ceefcb |
| 出典メモ | uspto-grants-1995_05 |