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3-Butenenitrile → 4,4-Dichloro-7-cyano-4-sila-1-heptene
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 3-Butenenitrile | HCID 8009 | — |
| 反応物 | Dichloro(prop-2-enyl)silane | HCID 77536 | — |
| 触媒 | Chloroplatinic acid | HCID 61859 | — |
| 溶媒 | Isopropanol | HCID 3776 | — |
| 生成物 | 4,4-Dichloro-7-cyano-4-sila-1-heptene | HCID 57136603 | 60,081.898% |
反応手順
Using the same apparatus and procedure described in EXAMPLE 1, 97.9 g (1.46 mol) of allyl cyanide and 350 μl of 1% chloroplatinic acid in isopropanol were added to the flask. Through the dropping funnel was added dropwise 20.6 g (0.15 mmol) of allyldichlorosilane for 30 min at 80° C. and the solution was further reacted for 17.5 hrs to complete the reaction. Vacuum distillation (76-78/0.5 torr) of the product mixture gave 18.76 g (62%) of 4,4-dichloro-7-cyano-4-sila-1-heptene.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05420323 |
| 出典データセット | uspto-grants-1995_05 |
| ORD ID | ord-c102ab6f06d446489d8d722786d7047c |
| 出典メモ | uspto-grants-1995_05 |