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Allyl glycidyl ether → 4,4-Dimethoxy-7-glycidoxy-4-sila-1-heptene
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Allyl glycidyl ether | HCID 7838 | — |
| 反応物 | Silane, dimethoxy-2-propenyl- | HCID 57370758 | — |
| 触媒 | Chloroplatinic acid | HCID 61859 | — |
| 溶媒 | Isopropanol | HCID 3776 | — |
| 生成物 | 4,4-Dimethoxy-7-glycidoxy-4-sila-1-heptene | HCID 57230503 | 43,023.801% |
反応手順
Using the same apparatus and procedure described in EXAMPLE 1, 12.1 g (0.11 mmol) of allylglycidyl ether and 60 μl of 1% chloroplatinic acid in isopropanol were added to the flask. Through the dropping funnel was added dropwise 6.6 g (0.05 mmol) of allyldimethoxysilane at 80° C. and the solution was further reacted for 2 hrs to complete the reaction. Vacuum distillation (83°-85° C.) of the product mixture gave 5.3 g (43.5%) of 4,4-dimethoxy-7-glycidoxy-4-sila-1-heptene.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05420323 |
| 出典データセット | uspto-grants-1995_05 |
| ORD ID | ord-e291784d8c894ca985aa7ae4f96346ae |
| 出典メモ | uspto-grants-1995_05 |