化工社化工社 化学情報印刷レポート · 研究参考用
Benzyl Alcohol → 1-(2-Bromophenyl)ethanol
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Benzyl Alcohol | HCID 244 | — |
| 反応物 | 2-Bromobenzyl alcohol | HCID 72850 | — |
| 反応物 | Tricyclohexyl [o-(1-hydroxyethyl)phenyl]tin | HCID 19359512 | — |
| 生成物 | 1-(2-Bromophenyl)ethanol | HCID 95455 | 75.1% |
反応手順
17.2 g of o-[tri(cyclohexyl)]tin]benzylalcohol was obtained in the same manner as in the synthesis of tricyclohexyl[o-(1-hydroxyethyl)phenyl]tin of Example 1-(4), with the exception that 9.40 g of o-bromobenzylalcohol (50.2 mmol), prepared in the aforementioned example (1), instead of o-bromo-1-phenyl ethanol (yield=75.1%).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US06022822 |
| 出典データセット | uspto-grants-2000_02 |
| ORD ID | ord-3367da7ec83a4b569278ddffb8d8c220 |
| 出典メモ | uspto-grants-2000_02 |