1,3-Dichlorobenzene → HCID 12127967、化合物

HRID 377058

反応式

HRID 377058 の反応式
[Cl:1][C:2]1[CH:7]=[CH:6][CH:5]=[C:4]([Cl:8])[CH:3]=1.[Cl-:9].[Al+3].[Cl-:11].[Cl-].Cl[CH:14]([Si:17]([Cl:20])([Cl:19])[Cl:18])[CH2:15]Cl>>[Cl:1][C:2]1[CH:3]=[C:4]([Cl:8])[CH:5]=[CH:6][C:7]=1[CH:15]([C:2]1[CH:7]=[CH:6][C:5]([Cl:9])=[CH:4][C:3]=1[Cl:11])[CH2:14][Si:17]([Cl:20])([Cl:19])[Cl:18]

参加物

4

反応物 3

HCID 109431,3-DichlorobenzeneHCID 79093Silane, trichloro(1,2-dichloroethyl)-HCID 6451240Aluminum(III) Chloride

生成物 1

HCID 12127967HCID 12127967、化合物収率 187.2%

実験手順

In the same apparatus and procedures as EXAMPLE 1 above, 49.1 ml (430 mmol) of 1,3-dichlorobenzene and 2.30 g (17.2 mmol) of aluminum chloride were alkylated with 19.40 g (83.5 mmol) of (1,2-dichloroethyl)trichlorosilane for 30 min at 120° C. The aluminum chloride catalyst was quenched with POCl3 and then stirred for another 1 hour to complete the deactivation. Freshly distilled hexane (100 ml) was added to the reaction mixture and insoluble solids in hexane were filtered from the organic soultion. After hexane was distilled, the reaction products were vacuum distilled to give 14.6 g of [2,2-bis(2,4-dichlorophenyl)ethyl]trichlorosilane (bp; 175-180° C./0.5 torr, yield; 39%).

後処理

  1. customThe aluminum chloride catalyst was quenched with POCl3
  2. additionFreshly distilled hexane (100 ml) was added to the reaction mixture and insoluble solids in hexane
  3. filtrationwere filtered from the organic soultion
  4. distillationAfter hexane was distilled
  5. distillationdistilled

出典と根拠

ORDレコード
ord-6deb113de3da4c4093a0c08eb6110b20
出典データセット
uspto-grants-2000_02
特許番号
US06022987

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