Methylhydroquinone → 1-Heptadecene

HRID 378198ノート

反応式

HRID 378198 の反応式
[CH3:1][CH2:2][CH:3]=[CH:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12].C[C:14]1[CH:20]=[C:19](O)C=[CH:17][C:15]=1O>CO>[CH2:1]=[CH:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:17][CH2:15][CH2:14][CH2:20][CH3:19]

参加物

4

反応物 2

HCID 7253MethylhydroquinoneHCID 1372853-Dodecen2 回

生成物 1

HCID 232171-Heptadecene

試薬・触媒・溶媒 1

HCID 887Methanol溶媒

実験手順

8-methoxycarboniltetracyclo[4.4.0.12,5.117,10 ]-3-dodecen of 65 grams, dicyclopentadien of 87 grams and methylhydroquinon of 0.14 gram were mixed in a 300 milli-litter eggplant type flask, and the reaction was continued at 170 degrees to 180 degrees in centigrade for 17 hours. The reaction product remained cooled, and residual 8-methoxycarboniltetracyclo[4.4.0.12,5.117,10 ]-3-dodecen and residual dicyclopentadien were distillated in vacuum. Hot methanol was added to the residue, and insoluble content was filtrated. The filtrate was concentrated in vacuum, and residue was recrystallized from methanol. Then, we obtained white crystal of 12-methoxycarbonilhexacyclo[6.6.1.13,6.110,13.02,7.09,14 ]heptadecen of 10 grams.

後処理

  1. temperatureThe reaction product remained cooled
  2. filtrationwas filtrated
  3. concentrationThe filtrate was concentrated in vacuum, and residue
  4. customwas recrystallized from methanol

出典と根拠

ORDレコード
ord-314850862b6b497d9479faee6bc2a512
出典データセット
uspto-grants-2000_02
特許番号
US06030747

反応ノート

読み込み中…