関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | 2,3-Dihydroxybutanedioic Acid | HCID 875 | — |
| 反応物 | 2-ethylhexanoic acid tin(II) salt | HCID 9318 | — |
| 反応物 | epsilon-CAPROLACTONE | HCID 10401 | — |
| 反応物 | Glycolide | HCID 65432 | — |
| 生成物 | Poliglecaprone | HCID 65431 | — |
反応手順
Glycolide (0.08865 moles) was mixed with ε-caprolactone (1.455 moles) and a catalytic amount of stannous octoate (0.3 moles) and tartaric acid (0.075 moles). The system was heated at 150° C. and was stirred at this temperature for 6 hours. At the conclusion of the reaction, the unreacted monomer was removed by heating at 120° C. under reduced pressure for 30 minutes. The resulting polymer had a peak melting temperature of 49.1° C. as measured by DSC and an Mw of 151,948 as measured by GPC.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US06299631B1 |
|---|
| 出典データセット | uspto-grants-2001_10 |
|---|
| ORD ID | ord-b319a34dd22e476b97bb99b4f886e3ff |
|---|
| 出典メモ | uspto-grants-2001_10 |
|---|
