Triethylamine →
反応式
[P:1]([Cl:5])([Cl:4])([Cl:3])=[O:2].[CH2:6]([CH:13]([CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH3:24])[CH2:14]O)[CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12].C(N([CH2:30][CH3:31])CC)C>CCCCCC>[CH2:6]([CH:13]([CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH3:24])[CH2:14][ClH:3][P:1]([ClH:5][CH2:14][CH:13]([CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:30][CH3:31])[CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH3:24])([Cl:4])=[O:2])[CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12]参加物
4
反応物 3
生成物 0
生成物のデータはまだありません。
試薬・触媒・溶媒 1
反応条件
- 温度
- 0 °C
実験手順
To 14.6 g (0.095 mol) of phosphorus oxychloride in hexane, 51.4 g (0.190 mol) of 2-heptylundecyl alcohol, 19.2 g (0.190 mol) of triethylamine in hexane were added dropwise while maintaining the temperature at not higher than 0° C. After ripening the mixture at 25° C., a hydrochloric acid salt of triethylamine was removed by washing. The solvent was also removed to obtain 59.1 g (0.095 mol) of bis(2-heptylundecyl) phosphoric chloride (not less than 95% purity was confirmed by 31-NMR)