Sodium Perchlorate → 1-(Methoxymethyl)-1-methylpyrrolidin-1-ium perchlorate

HRID 383183

反応式

HRID 383183 の反応式
[Cl:1]([O-:5])(=[O:4])(=[O:3])=[O:2].[Na+].[Cl-].[CH3:8][N+:9]1([CH2:14][O:15][CH3:16])[CH2:13][CH2:12][CH2:11][CH2:10]1>C(O)C>[Cl:1]([O-:5])(=[O:4])(=[O:3])=[O:2].[CH3:16][O:15][CH2:14][N+:9]1([CH3:8])[CH2:13][CH2:12][CH2:11][CH2:10]1

参加物

4

反応物 2

HCID 522606Sodium PerchlorateHCID 23116042N-methoxymethyl-N-methylpyrrolidinium chloride

生成物 1

HCID 231160381-(Methoxymethyl)-1-methylpyrrolidin-1-ium perchlorate

試薬・触媒・溶媒 1

HCID 702Ethanol溶媒

実験手順

A 5.91 g quantity of sodium perchlorate (product of Wako Pure Chemical Ind. Ltd.) was dissolved in 77 g of ethyl alcohol, and 7.99 g of N-methoxymethyl-N-methylpyrrolidinium chloride was added to the solution. The mixture was reacted at room temperature for 1.5 hours, whereby the reaction was terminated. The resulting sodium chloride was filtered off, and the filtrate was concentrated and dried in a vacuum. The residue was dissolved in dichloromethane, the solution was again filtered with a membrane filter, and the filtrate was concentrated in a vacuum and dried, giving 10.94 g of the desired product.

後処理

  1. customThe mixture was reacted at room temperature for 1.5 hours
  2. customwhereby the reaction was terminated
  3. filtrationThe resulting sodium chloride was filtered off
  4. concentrationthe filtrate was concentrated
  5. customdried in a vacuum
  6. dissolutionThe residue was dissolved in dichloromethane
  7. filtrationthe solution was again filtered with a membrane
  8. filtrationfilter
  9. concentrationthe filtrate was concentrated in a vacuum
  10. customdried

出典と根拠

ORDレコード
ord-067845310e5f4c2590528862f9eebda8
出典データセット
uspto-grants-2013_02
特許番号
US08366956B2

関連ノート

読み込み中…