N-methoxymethyl-N-methylpyrrolidinium chloride → N-methoxymethyl-N-methylpyrrolidinium hexafluorophosphate

HRID 383189ノート

反応式

HRID 383189 の反応式
[Cl-].[CH3:2][O:3][CH2:4][N+:5]1([CH3:10])[CH2:9][CH2:8][CH2:7][CH2:6]1.[F:11][P-:12]([F:17])([F:16])([F:15])([F:14])[F:13].[K+]>O>[F:11][P-:12]([F:17])([F:16])([F:15])([F:14])[F:13].[CH3:2][O:3][CH2:4][N+:5]1([CH3:10])[CH2:9][CH2:8][CH2:7][CH2:6]1

参加物

4

反応物 2

HCID 23116042N-methoxymethyl-N-methylpyrrolidinium chlorideHCID 23688904Potassium hexafluorophosphate

生成物 1

HCID 86610880N-methoxymethyl-N-methylpyrrolidinium hexafluorophosphate

試薬・触媒・溶媒 1

HCID 962Water溶媒

実験手順

A 20.0 g quantity of N-methoxymethyl-N-methylpyrrolidinium chloride prepared in Example 10 was dissolved in 120 g of water, and 22.2 g of potassium hexafluorophosphate was added to the solution, whereupon a white solid separated out. The mixture was stirred for 30 minutes, and dichloromethane was thereafter added to the mixture for extraction. The organic layer was washed with 120 g of water six times and then dried, affording 25.1 g of a white solid as the desired product.

後処理

  1. customseparated out
  2. additiondichloromethane was thereafter added to the mixture for extraction
  3. washThe organic layer was washed with 120 g of water six times
  4. customdried

出典と根拠

ORDレコード
ord-d358d06cb88a4fa083a00347a5157da7
出典データセット
uspto-grants-2013_02
特許番号
US08366956B2

反応ノート

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