化工社化工社 化学情報印刷レポート · 研究参考用
Iodine → Muconic Acid
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Iodine | HCID 807 | — |
| 反応物 | (2E,4Z)-2,4-Hexadienedioic acid | HCID 5280614 | — |
| 溶媒 | 1-Propanol | HCID 1031 | — |
| 生成物 | Muconic Acid | HCID 5356793 | 73% |
反応手順
cis,trans-Muconic acid (103 mg, 0.725 mmol) is dissolved in n-propanol (10 mL) at room temperature and a crystal of iodine (10 mg, 0.04 mmol) is added. The reaction mixture is allowed to stir at room temperature for 24 hours. The precipitate is filtered, washed with acetonitrile and dried under reduced pressure to yield 75 mg of trans,trans-muconic acid, a 73 percent yield.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US08367858B2 |
| 出典データセット | uspto-grants-2013_02 |
| ORD ID | ord-43b6087262e946d986e929fdc93548e2 |
| 出典メモ | uspto-grants-2013_02 |