化工社化工社 化学情報印刷レポート · 研究参考用
Iodine → Muconic Acid
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Iodine | HCID 807 | — |
| 反応物 | (2E,4Z)-2,4-Hexadienedioic acid | HCID 5280614 | — |
| 溶媒 | 1-Butanol | HCID 263 | — |
| 生成物 | Muconic Acid | HCID 5356793 | 76.2% |
反応手順
cis,trans-Muconic acid (105 mg, 0.739 mmol) is dissolved in n-butanol (10 mL) at room temperature and a crystal of iodine (17 mg, 0.067 mmol) is added. The reaction mixture is allowed to stir at room temperature for 24 hours. The precipitate is filtered, washed with ice-cold acetonitrile and dried under reduced pressure to yield 80 mg of trans,trans-muconic acid, a 76 percent yield.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US08367858B2 |
| 出典データセット | uspto-grants-2013_02 |
| ORD ID | ord-71794a6dd7aa418083ef1ace501e0555 |
| 出典メモ | uspto-grants-2013_02 |