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Benzyl azide → (1-benzyl-1H-1,2,3-triazol-5-yl)diphenylmethanol
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Benzyl azide | HCID 12152 | — |
| 反応物 | Diphenylethynylcarbinol | HCID 92976 | — |
| 触媒 | Chlororuthenium(1+) 1,2,3,4,5-pentamethylcyclopenta-2,4-dien-1-ide--triphenylphosphane (1/1/2) | HCID 71310463 | — |
| 溶媒 | Benzene | HCID 241 | — |
| 生成物 | (1-benzyl-1H-1,2,3-triazol-5-yl)diphenylmethanol | HCID 68431884 | — |
反応手順
Benzyl azide (0.200 g, 1.50 mmol), 1,1-diphenyl-2-propyn-1-ol (0.344 g, 1.65 mmol), Cp*RuCl(PPh3)2 (12 mg, 0.015 mmol). Solvent, benzene; reaction temperature, 80° C.; reaction time, 4 hours; yield, 0.39 g (75%). The reaction was performed under air. EI-MS: m/z 342 [M+1].
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US08372986B2 |
| 出典データセット | uspto-grants-2013_02 |
| ORD ID | ord-872830791699454a8d5a26150a5d49ec |
| 出典メモ | uspto-grants-2013_02 |