Erythritol → Sucrose

HRID 388183

反応式

HRID 388183 の反応式
OC1[C@@H]([C@@H](O)CO)OC(=O)C=1O.[CH3:13][C@:14]12[C@@H:23]3[CH2:24][CH2:25][C@@:26]4([O:31][C@@H:32]5[O:37][C@H:36]([CH2:38][OH:39])[C@@H:35]([OH:40])[C@H:34]([OH:41])[C@H:33]5[O:42][C@@H:43]5[O:48][C@H:47]([CH2:49][OH:50])[C@@H:46]([OH:51])[C@H:45]([O:52][C@@H:53]6[O:58][C@H:57]([CH2:59][OH:60])[C@@H:56]([OH:61])[C@H:55]([OH:62])[C@H:54]6[OH:63])[C@H:44]5[OH:64])[C:28]([CH2:30][C@@:22]3([CH2:27]4)[CH2:21][CH2:20][C@@H:19]1[C@@:18]([C:66]([O:68][C@@H:69]1[O:74][C@H:73]([CH2:75][OH:76])[C@@H:72]([OH:77])[C@H:71]([OH:78])[C@H:70]1[OH:79])=[O:67])([CH3:65])[CH2:17][CH2:16][CH2:15]2)=[CH2:29].C(O)[C@@H]([C@@H](CO)O)O>>[CH3:13][C@:14]12[C@@H:23]3[CH2:24][CH2:25][C@@:26]4([O:31][C@@H:32]5[O:37][C@H:36]([CH2:38][OH:39])[C@@H:35]([OH:40])[C@H:34]([OH:41])[C@H:33]5[O:42][C@@H:43]5[O:48][C@H:47]([CH2:49][OH:50])[C@@H:46]([OH:51])[C@H:45]([O:52][C@@H:53]6[O:58][C@H:57]([CH2:59][OH:60])[C@@H:56]([OH:61])[C@H:55]([OH:62])[C@H:54]6[OH:63])[C@H:44]5[OH:64])[C:28]([CH2:30][C@@:22]3([CH2:27]4)[CH2:21][CH2:20][C@@H:19]1[C@@:18]([C:66]([O:68][C@@H:69]1[O:74][C@H:73]([CH2:75][OH:76])[C@@H:72]([OH:77])[C@H:71]([OH:78])[C@H:70]1[OH:79])=[O:67])([CH3:65])[CH2:17][CH2:16][CH2:15]2)=[CH2:29].[CH2:49]([OH:50])[C@H:47]1[O:48][C@H:43]([O:42][C@:33]2([CH2:32][OH:31])[O:37][C@H:36]([CH2:38][OH:39])[C@@H:35]([OH:40])[C@@H:34]2[OH:41])[C@H:44]([OH:64])[C@@H:45]([OH:52])[C@@H:46]1[OH:51]

参加物

5

反応物 3

HCID 222285ErythritolHCID 44564215[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl] (1R,4S,5R,9S,10R,13S)-13-[(2S,3R,4S,5S,6R)-3-[(2S,3R,4S,5R,6R)-3,5-dihydroxy-6-(hydroxymethyl)-4-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]oxy-4,5-dihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy-5,9-dimethyl-14-methylidenetetracyclo[11.2.1.01,10.04,9]hexadecane-5-carboxylateHCID 54670067L-Ascorbic Acid

生成物 2

HCID 5988Sucrose収率 10%HCID 44564215[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl] (1R,4S,5R,9S,10R,13S)-13-[(2S,3R,4S,5S,6R)-3-[(2S,3R,4S,5R,6R)-3,5-dihydroxy-6-(hydroxymethyl)-4-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]oxy-4,5-dihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy-5,9-dimethyl-14-methylidenetetracyclo[11.2.1.01,10.04,9]hexadecane-5-carboxylate

実験手順

A rebaudioside A diet lemon-lime beverage (sweetness level 10% sucrose equivalent) is prepared with 50 mg of vitamin C per serving (˜240 mL), 3 mg of vitamin E, 400 ppm of rebaudioside A, and 3.5% erythritol.

出典と根拠

ORDレコード
ord-28daefe1384b4c9d8a55997d58b847bd
出典データセット
uspto-grants-2013_02
特許番号
US08377491B2

関連ノート

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