関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | 1,4-Dichlorobenzene | HCID 4685 | — |
| 反応物 | 3H-Indole, 2,3,3-trimethyl- | HCID 15427 | — |
| 反応物 | 1-(Iodomethyl)-3,5-dinitrobenzene | HCID 22609073 | — |
| 生成物 | 1-(3,5-dinitrobenzyl)-2,3,3-trimethyl-3H-indolium iodide | HCID 17902140 | 55.9% |
反応手順
To 2,3,3-trimethylindolenine (1.64 g) was added 3,5-dinitrobenzyl iodide (3.71 g) and dichlorobenzene (15 ml). After heating to 90° C. for 6 hours the mixture was allowed to cool and the resultant precipitate removed by filtration. The solid was washed with dichlorobenzene (2×10 ml) and ether (2×50 ml). The material was dried in a vacuum oven to give the product as a yellow solid (2.69 g).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US08378120B2 |
|---|
| 出典データセット | uspto-grants-2013_02 |
|---|
| ORD ID | ord-754140fff8a546979a083679d9b20aac |
|---|
| 出典メモ | uspto-grants-2013_02 |
|---|
