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1,3-Cyclohexanediol → 3-(Tert-butyldimethylsilyl)oxy-1-cyclohexanol
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 1,3-Cyclohexanediol | HCID 10433 | — |
| 反応物 | 2-[3-(tert-butyldimethylsilanyloxy)-cyclopentyl]-4-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-1H-pyrazole | HCID 66759519 | — |
| 生成物 | 3-(Tert-butyldimethylsilyl)oxy-1-cyclohexanol | HCID 557077 | 35% |
反応手順
The title compound was prepared in 35% yield from 1,3-cyclohexanediol by a procedure analogous to Intermediate 28, Step A. 1H NMR (300 MHz, CDCl3): δ 4.0-4.2 (m, 1H), 3.8-3.95 (m, 1H), 1.3-2.4 (m, 9H), 0.86 (s, 9H), 0.05 (s, 6H).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US08378104B2 |
| 出典データセット | uspto-grants-2013_02 |
| ORD ID | ord-952be78ea2404a4b9f2eea420bff95c3 |
| 出典メモ | uspto-grants-2013_02 |