関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Methacrylic Acid | HCID 4093 | — |
| 反応物 | Methyl Methacrylate | HCID 6658 | — |
| 反応物 | Benzyl methacrylate | HCID 17236 | — |
| 反応物 | 2-Methoxyethyl acrylate | HCID 18392 | — |
| 反応物 | 1,1'-Dimethyl 2,2'-(1,2-diazenediyl)bis(2-methylpropanoate) | HCID 75763 | — |
| 溶媒 | Methyl Ethyl Ketone | HCID 6569 | — |
| 生成物 | Methyl methacrylate methoxyethyl acrylate benzyl methacrylate methacrylic acid | HCID 131730237 | — |
反応手順
360.0 g of methyl ethyl ketone was introduced into a 2-liter three-mouthed flask equipped with an agitator, a thermometer, a circulation cooling tube, and a nitrogen gas inlet tube, and was heated to 75° C. To this was added a mixed liquid comprising 180 g of methyl methacrylate, 32.4 g of methoxyethyl acrylate, 126.0 g of benzyl methacrylate, 21.6 g of methacrylic acid, 72 g of methylethyl ketone, and 1.44 g of “V-601” (manufactured by Wako Pure Chemical Industries Co., Ltd.), this mixed liquid being added dropwise at a uniform rate so as to complete dropping over two hours. When the dropwise addition was completed, a solution comprising 0.72 g of “V-601” and 36.0 g of methylethyl ketone was added, agitation was carried out for 2 hours at 75° C. and a solution comprising 0.72 g of “V-601” and 36.0 g of methylethyl ketone was also added and agitation was carried out for two hours at 75° C. Thereupon, agitation was continued for a further two hours at a raised temperature of 85° C., to yield a resin solution of a copolymer of methyl methacrylate/methoxyethyl acrylate/benzyl methacrylate/methacrylic acid (=50/9/35/6 (weight ratio)).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| 特許番号 | US08382230B2 |
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| 出典データセット | uspto-grants-2013_02 |
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| ORD ID | ord-7f02931adc7844f39e6b8158f2e02c7b |
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| 出典メモ | uspto-grants-2013_02 |
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