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HRID 389788作成日:2026年10月26日

Methacrylic Acid → Methyl methacrylate methoxyethyl acrylate benzyl methacrylate methacrylic acid

https://huagongshe.com/reaction/389788

反応式

関与物質

役割名称HCID仕込み量
反応物Methacrylic AcidHCID 4093—
反応物Methyl MethacrylateHCID 6658—
反応物Benzyl methacrylateHCID 17236—
反応物2-Methoxyethyl acrylateHCID 18392—
反応物1,1'-Dimethyl 2,2'-(1,2-diazenediyl)bis(2-methylpropanoate)HCID 75763—
溶媒Methyl Ethyl KetoneHCID 6569—
生成物Methyl methacrylate methoxyethyl acrylate benzyl methacrylate methacrylic acidHCID 131730237—

反応条件

温度75 °C

反応手順

360.0 g of methyl ethyl ketone was introduced into a 2-liter three-mouthed flask equipped with an agitator, a thermometer, a circulation cooling tube, and a nitrogen gas inlet tube, and was heated to 75° C. To this was added a mixed liquid comprising 180 g of methyl methacrylate, 32.4 g of methoxyethyl acrylate, 126.0 g of benzyl methacrylate, 21.6 g of methacrylic acid, 72 g of methylethyl ketone, and 1.44 g of “V-601” (manufactured by Wako Pure Chemical Industries Co., Ltd.), this mixed liquid being added dropwise at a uniform rate so as to complete dropping over two hours. When the dropwise addition was completed, a solution comprising 0.72 g of “V-601” and 36.0 g of methylethyl ketone was added, agitation was carried out for 2 hours at 75° C. and a solution comprising 0.72 g of “V-601” and 36.0 g of methylethyl ketone was also added and agitation was carried out for two hours at 75° C. Thereupon, agitation was continued for a further two hours at a raised temperature of 85° C., to yield a resin solution of a copolymer of methyl methacrylate/methoxyethyl acrylate/benzyl methacrylate/methacrylic acid (=50/9/35/6 (weight ratio)).

情報源と証拠

DOI10.6084/m9.figshare.5104873.v1
特許番号US08382230B2
出典データセットuspto-grants-2013_02
ORD IDord-7f02931adc7844f39e6b8158f2e02c7b
出典メモuspto-grants-2013_02