Hydrazine → HCID 12366387、化合物
反応式
[CH:1](=[C:8]1[C:16]2[C:11](=[CH:12][CH:13]=[C:14]([Br:17])[CH:15]=2)[C:10](=O)[O:9]1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[NH2:19][NH2:20]>C(O)C>[CH2:1]([C:8]1[C:16]2[C:11](=[CH:12][CH:13]=[C:14]([Br:17])[CH:15]=2)[C:10](=[O:9])[NH:20][N:19]=1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1参加物
4
実験手順
To a solution of EXAMPLE 1D (778 mg, 2.58 mmol) in ethanol (10 mL) was added hydrazine (83 mg, 2.58 mmol) and the mixture was refluxed for 2 hours. After cooling, the precipitated solid was collected by filtration and dried under vacuum to yield the title compound. MS (ESI) m/z 316 (M+H)+.
後処理
- temperaturethe mixture was refluxed for 2 hours
- temperatureAfter cooling
- filtrationthe precipitated solid was collected by filtration
- customdried under vacuum
出典と根拠
- ORDレコード
- ord-b86b2683ce9d4febae8f56342358b8ac
- 出典データセット
- uspto-grants-2013_02
- 特許番号
- US08383623B2
反応ノート
読み込み中…