1,3-Dimethyl-2-imidazolidinone → Anthraquinone

HRID 392491

反応式

HRID 392491 の反応式
N[C:2]1[C:15]2[C:14](=[O:16])[C:13]3[C:8](=[CH:9][CH:10]=[CH:11][CH:12]=3)[C:7](=[O:17])[C:6]=2[C:5](O)=[CH:4][C:3]=1Cl.CN1CCN(C)C1=O.C(=O)([O-])[O-].[K+].[K+].C(N(CCCCCCCC)C1C=C(O)C=CC=1)CCCCCCC>O>[CH:9]1[C:8]2[C:7](=[O:17])[C:6]3[C:15](=[CH:2][CH:3]=[CH:4][CH:5]=3)[C:14](=[O:16])[C:13]=2[CH:12]=[CH:11][CH:10]=1

参加物

6

反応物 4

HCID 66611,3-Dimethyl-2-imidazolidinoneHCID 11430Potassium CarbonateHCID 755909,10-Anthracenedione, 1-amino-2-chloro-4-hydroxy-HCID 15734569N,N-di-n-octyl-m-aminophenol

生成物 1

HCID 6780Anthraquinone

試薬・触媒・溶媒 1

HCID 962Water溶媒

反応条件

温度
150 °C

実験手順

One part of 1-amino-2-chloro-4-hydroxyanthraquinone, 10 parts of 1,3-dimethyl-2-imidazolidinone, 1.0 part of potassium carbonate and 2.0 parts of N,N-di-n-octyl-m-aminophenol were mixed at room temperature, and then heated to 150° C. While this temperature was maintained, the reaction was conducted for 5 hours. The reaction mixture was cooled, then charged into 100 parts of water, extracted with toluene and thereafter purified through silica gel column chromatography to obtain an anthraquinone compound as coloring matter No. 1 (yield 90%).

後処理

  1. temperatureWhile this temperature was maintained
  2. temperatureThe reaction mixture was cooled
  3. extractionextracted with toluene
  4. custompurified through silica gel column chromatography

出典と根拠

ORDレコード
ord-b0de88bf3ad0455f953ed20c84cbbac2
出典データセット
uspto-grants-2004_10
特許番号
US06800674B2

関連ノート

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