化工社化工社 化学情報印刷レポート · 研究参考用
Benzylamine → HCID 178418897、化合物
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Benzylamine | HCID 7504 | — |
| 反応物 | Ethyl thiocyanate | HCID 10968 | — |
| 反応物 | Sodium Hydroxide | HCID 14798 | — |
| 反応物 | Trimethylsilyl triflate | HCID 65367 | — |
| 生成物 | HCID 178418897 | HCID 178418897 | 100% |
反応手順
Benzylamine (13.8 mg) was dissolved in ethyl thiocyanate (50 μl). To this solution, trimethylsilyl trifluoromethanesulfonate (25.7 μl) was added dropwise at room temperature. After continued stirring for 1 day at room temperature, 2N aqueous sodium hydroxide was added to the solution, which was then extracted with ethyl acetate. The ethyl acetate layer was dried over anhydrous sodium sulfate and concentrated under reduced pressure to give the titled compound (25.4 mg, yield 100%).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US06803472B2 |
| 出典データセット | uspto-grants-2004_10 |
| ORD ID | ord-5e2bce3b596444639f46832804cd3c6f |
| 出典メモ | uspto-grants-2004_10 |