Benzyl Benzoate → Potassium Benzoate

HRID 3938

反応式

HRID 3938 の反応式
[C:1]([O:9]CC1C=CC=CC=1)(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.C[Si](C)(C)[O-].[K+:22]>CCOCC>[C:1]([O-:9])(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[K+:22]

参加物

4

反応物 2

HCID 2345Benzyl BenzoateHCID 23668039Potassium trimethylsilanolate

生成物 1

HCID 23661960Potassium Benzoate収率 73.7%

試薬・触媒・溶媒 1

HCID 3283Diethyl Ether溶媒

実験手順

The procedure of Example 1 was followed using benzyl benzoate (9.6 mL, 50 mmol), potassium trimethylsilanolate (6.42 g, 50 mmol), dry ether (150 mL), and a 2 h reaction mixture. Potassium benzoate (5.9 g, 73% yield) was isolated as a white solid: 1H NMR (D2O) δ 7.1-8.0 ppm (m, Ar--H's, 5H). Anal. Calcd. for C7H5KO2 : C, 52.48; H, 3.15; K, 24.61. Found: C, 50.53, 50.76; H, 3.40, 3.21; K, 25.60, 25.50.

後処理

  1. customa 2 h reaction mixture

出典と根拠

ORDレコード
ord-a3fe8da2ee984deab1f5616cd4413322
出典データセット
uspto-grants-1988_02
特許番号
US04723016

関連ノート

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