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Methyl 4-chlorobenzoate → Potassium 4-chlorobenzoate
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Methyl 4-chlorobenzoate | HCID 14307 | — |
| 反応物 | Potassium trimethylsilanolate | HCID 23668039 | — |
| 溶媒 | Diethyl Ether | HCID 3283 | — |
| 生成物 | Potassium 4-chlorobenzoate | HCID 23664289 | 84.1% |
反応手順
The procedure of Example 1 was followed using methyl 4-chlorobenzoate (13.65 g, 80 mmol), potassium trimethylsilanolate (10.26 g, 80 mmol), dry ether (500 mL) and a 4 h reaction time. Potassium 4-chlorobenzoate (13.1 g, 84% yield) was isolated as a white solid: 1H NMR (D2O, DSS, 80 MHz) δ 7.68 ppm (ABq, Δν1-3 =29 Hz, J=8.5 Hz, Ar--H's, 4H). Anal. Calcd. for C7H4ClKO2 : C, 43.19; H, 2.07. Found: C, 43.27; H, 2.33.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04723016 |
| 出典データセット | uspto-grants-1988_02 |
| ORD ID | ord-ee16a2a12b5a4c94a18c4647c3615c25 |
| 出典メモ | uspto-grants-1988_02 |