2,3,3,3-Tetrafluoro-2-(1,1,2,2,3,3,3-heptafluoropropoxy)propanoyl fluoride → Sodium 2,3,3,3-tetrafluoro-2-(heptafluoropropoxy)propanoate

HRID 3950

反応式

HRID 3950 の反応式
[F:1][C:2]([C:17]([F:20])([F:19])[F:18])([O:6][C:7]([F:16])([F:15])[C:8]([F:14])([F:13])[C:9]([F:12])([F:11])[F:10])[C:3](F)=[O:4].C[Si](C)(C)[O-:23].[Na+:26]>C1(C)C=CC=CC=1>[F:1][C:2]([C:17]([F:18])([F:19])[F:20])([O:6][C:7]([F:15])([F:16])[C:8]([F:13])([F:14])[C:9]([F:12])([F:10])[F:11])[C:3]([O-:4])=[O:23].[Na+:26]

参加物

4

反応物 2

HCID 1027402,3,3,3-Tetrafluoro-2-(1,1,2,2,3,3,3-heptafluoropropoxy)propanoyl fluorideHCID 23672319Sodium trimethylsilanolate

生成物 1

HCID 3765118Sodium 2,3,3,3-tetrafluoro-2-(heptafluoropropoxy)propanoate収率 66%

試薬・触媒・溶媒 1

HCID 1140Toluene溶媒

実験手順

The procedure of Example 1 was followed using perfluoro-2-methyl-3-oxahexanoyl fluoride (33.2 g, 0.1 mol), sodium trimethylsilanolate (11.2 g, 0.1 mol), dry toluene (200 mL), and 1.5 h of heating at reflux. Sodium perfluoro-2-methyl-3-oxahexanoate (23.1 g, 66% yield) was isolated as a white solid: The 19F NMR data were the same as reported in Example 15. Anal. Calcd. for C6F11NaO3 : C, 19.77; H, 57.33; Na, 7.63. Found: C, 19.56; H, 56.93; Na, 7.80.

後処理

  1. temperatureof heating
  2. temperatureat reflux

出典と根拠

ORDレコード
ord-13e5debefb0d4b96963cdfe09db40762
出典データセット
uspto-grants-1988_02
特許番号
US04723016

関連ノート

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