Tert-butyl-(4-oxiranylmethoxy-phenoxy)-diphenylsilane → HCID 69987371、化合物
反応式
C(O)=O.[NH2:4][CH2:5][CH2:6][C:7]1[CH:26]=[CH:25][C:10]([NH:11][CH:12]2[CH2:17][CH2:16][N:15]([C:18](=[O:24])[CH2:19][CH2:20][CH2:21][CH2:22][CH3:23])[CH2:14][CH2:13]2)=[CH:9][CH:8]=1.C([Si]([O:44][C:45]1[CH:50]=[CH:49][C:48]([O:51][CH2:52][CH:53]2[CH2:55][O:54]2)=[CH:47][CH:46]=1)(C1C=CC=CC=1)C1C=CC=CC=1)(C)(C)C>>[OH:54][C@H:53]([CH2:52][O:51][C:48]1[CH:49]=[CH:50][C:45]([OH:44])=[CH:46][CH:47]=1)[CH2:55][NH:4][CH2:5][CH2:6][C:7]1[CH:26]=[CH:25][C:10]([NH:11][CH:12]2[CH2:17][CH2:16][N:15]([C:18](=[O:24])[CH2:19][CH2:20][CH2:21][CH2:22][CH3:23])[CH2:14][CH2:13]2)=[CH:9][CH:8]=1参加物
3
実験手順
1-{4-[4-(2-Aminoethyl)anilino]-1-piperidinyl}-1-hexanone formate (0.234 g, 0.645 mmol) was reacted with tert-butyl-(4-oxiranylmethoxy-phenoxy)-diphenyl-silane (0.26 g, 0.644 mmol) according to Procedure G to give the title compound (0.13 g, 0.180 mmol).
出典と根拠
- ORDレコード
- ord-16756c37547149cb9640b0979a3881bf
- 出典データセット
- uspto-grants-2003_08
- 特許番号
- US06605618B2