化工社化工社 化学情報印刷レポート · 研究参考用
Monoepoxycyclododecadiene → Cyclododecanol
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Monoepoxycyclododecadiene | HCID 54352584 | — |
| 反応物 | HCID 178418361 | HCID 178418361 | — |
| 触媒 | Palladium | HCID 23938 | — |
| 生成物 | Cyclododecanol | HCID 15595 | 20% |
反応手順
In a reaction example shown in this report, when epoxycyclododecadiene is subjected to a reduction reaction with a hydrogen gas in the presence of a palladium catalyst carried on γ-alumina under a reduced pressure of 1.3 MPa at a reaction temperature of 90° C., cyclododecanol is obtained at a yield of 20%. In the report, a palladium catalyst carried on titania and a palladium catalyst carried on silica were employed. In each case, the yield of the cyclododecanol was less than 20%.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US06608235B1 |
| 出典データセット | uspto-grants-2003_08 |
| ORD ID | ord-d0480ba8cfda4206b9d3c84575546c15 |
| 出典メモ | uspto-grants-2003_08 |