関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Hydrochloric Acid | HCID 313 | — |
| 反応物 | Diethyl Ether | HCID 3283 | — |
| 反応物 | Cyclopropanecarbonitrile | HCID 79637 | — |
| 溶媒 | Ethanol | HCID 702 | — |
| 生成物 | Ethyl cyclopropanecarboximidate hydrochloride | HCID 20026660 | 59% |
反応手順
A steady stream of HCl gas was slowly passed through a solution of cyclopropancarbonitril (25 g, 373 mmol) in EtOH (17.2 ml). After 15 h the reaction mixture was cooled to 0° C. and diethylether was added dropwise. The precipitated title compound was filtered and obtained as a colourless crystalline material (32.9 g, 220 mmol, 59%). MS: m/e=112.2 (M−H).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US06610723B2 |
|---|
| 出典データセット | uspto-grants-2003_08 |
|---|
| ORD ID | ord-82b83684b24e4704b279c0b7d2caca4b |
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| 出典メモ | uspto-grants-2003_08 |
|---|
