化工社化工社 化学情報印刷レポート · 研究参考用
1-Hexanol → N1-(1-Methylethyl)-1,4-benzenediamine
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 1-Hexanol | HCID 8103 | — |
| 反応物 | Sodium Hydroxide | HCID 14798 | — |
| 反応物 | N-isopropyl-4-nitrosoaniline | HCID 21909787 | — |
| 生成物 | N1-(1-Methylethyl)-1,4-benzenediamine | HCID 85306 | — |
反応手順
Following essentially the procedure of Example 1, 66.0 g (0.25 mole) N-isopropyl-4-nitrosoaniline, 20 g (50%) sodium hydroxide and 264 g n-hexanol were kept at 100° C. for 1.5 hours. HPLC analysis of the reaction mixture indicated absence of the nitroso starting compound. By vacuum distillation (95°-101° C. at 13.3-26.6 Pa), 31.3 g of product were recovered (48.6 wt. % yield).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04723040 |
| 出典データセット | uspto-grants-1988_02 |
| ORD ID | ord-c383faf3f6174cd6aefc2d5b32c406fe |
| 出典メモ | uspto-grants-1988_02 |