1(N,N-dimethylaminoethyl)indene → HCID 178483377、化合物

HRID 398256ノート

反応式

HRID 398256 の反応式
[CH3:1][N:2]([CH2:4][CH2:5][CH:6]1[C:14]2[C:9](=[CH:10][CH:11]=[CH:12][CH:13]=2)[CH:8]=[CH:7]1)[CH3:3].CN(CCC1CC=CC=1)C.[Cl-:25].[Cl-].[Cl-].[CH:28]1([Zr+3:33])[CH:32]=[CH:31][CH:30]=[CH:29]1.[Cl-].[Cl-].[Cl-].C[Zr](C)(C)(C)(C)C1C=CC=C1>>[Cl-:25].[Cl-:25].[CH3:1][N:2]([CH2:4][CH2:5][CH:6]1[C:14]2[C:9](=[CH:10][CH:11]=[CH:12][CH:13]=2)[CH:8]=[C:7]1[Zr+2:33][CH:28]1[CH:32]=[CH:31][CH:30]=[CH:29]1)[CH3:3]

参加物

5

反応物 4

HCID 119880011(N,N-dimethylaminoethyl)indeneHCID 12154709(N,N-dimethylaminoethyl)cyclopentadieneHCID 178477801HCID 178477801、化合物HCID 178478629HCID 178478629、化合物

生成物 1

HCID 178483377HCID 178483377、化合物収率 35%

実験手順

Example 1 was repeated in the same manner as described except that 1(N,N-dimethylaminoethyl)indene was substituted for (N,N-dimethylaminoethyl)cyclopentadiene and that cyclopentadienylzirconium trichloride was substituted for pentamethylcyclopentadienylzirconium trichloride. The yield was 35.0%. The physical properties of the product are as follows:

出典と根拠

ORDレコード
ord-3b0cd03279b84492bcc83f1f6706ec1a
出典データセット
uspto-grants-2003_08
特許番号
US06610872B1

反応ノート

読み込み中…