Dimethylformamide → HCID 54259741、化合物

反応式

[C:1]([C:3]1[CH:8]=[C:7]([CH3:9])[C:6]([N+:10]([O-:12])=[O:11])=[CH:5][N:4]=1)#[N:2].[CH3:13][N:14]([CH:16]=O)[CH3:15]>>[C:1]([C:3]1[CH:8]=[C:7]([CH:9]=[CH:13][N:14]([CH3:16])[CH3:15])[C:6]([N+:10]([O-:12])=[O:11])=[CH:5][N:4]=1)#[N:2]

参加物

反応物 2

HCID 6228Dimethylformamide

HCID 230001712-Cyano-4-methyl-5-nitropyridine

生成物 1

HCID 54259741HCID 54259741、化合物

実験手順

A stirred solution of 2-cyano-4-methyl-5-nitropyridine (2.48 g, 15.2 mmol) in DMF (10 mL) and DMF-dimethylacetal (2.7 mL, 20 mmol) was heated to 90° C. for two h. The solution was cooled and evaporated in vacuo to give the title compound as a deep red solid:

後処理

temperatureThe solution was cooled
customevaporated in vacuo

出典と根拠

ORDレコード: ord-29dd05ebc4b9480cae3bc0def21340b0
出典データセット: uspto-grants-2003_08
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US06610692B1

反応ノート

読み込み中…

参加物