化工社化工社 化学情報印刷レポート · 研究参考用
Lactic Acid → (2R,3S,4R,5R)-2,3,4,5,6-pentahydroxyhexanal
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Lactic Acid | HCID 612 | — |
| 反応物 | Glyceric acid | HCID 752 | — |
| 反応物 | Glycolic Acid | HCID 757 | — |
| 反応物 | Carbonic Acid | HCID 767 | — |
| 反応物 | Oxalic Acid | HCID 971 | — |
| 反応物 | Erythronic acid | HCID 2781043 | — |
| 生成物 | (2R,3S,4R,5R)-2,3,4,5,6-pentahydroxyhexanal | HCID 107526 | 25% |
反応手順
This type of alkaline oxidative degradation, which is 25 effective both on hemiacetal functions and on ketone functions, also entails the formation of by-products such as, in particular, carbonic acid, oxalic acid, glyceric acid, glycolic acid, lactic acid, erythronic acid and, of course, fornic acid, which are obtained in a molar yield of about 25% from glucose when the alkalinity conditions are such that they allow a 75% yield of arabinonate. Formic acid is always produced in yields close to 100% of the stoichiometry.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05817780 |
| 出典データセット | uspto-grants-1998_10 |
| ORD ID | ord-7c204958a2f44b7ea5aa2ea832301073 |
| 出典メモ | uspto-grants-1998_10 |