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Oxygen → D-Arabinonic acid
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Oxygen | HCID 977 | — |
| 反応物 | (2R,3S,4R,5R)-2,3,4,5,6-pentahydroxyhexanal | HCID 107526 | — |
| 溶媒 | Methanol | HCID 887 | — |
| 生成物 | D-Arabinonic acid | HCID 122045 | 78% |
反応手順
As a comparative example, it will be noted that Vuorinen et al. (Starke, 43 No. 5, pp. :94-198), in carrying out the oxidation of glucose without methanol, had to use a pressure of pure oxygen of 26 bar in order to obtain an arabinonic acid yield of 78% only with 3.5% and 6.5% impurities consisting of glyceric acid and glycolic acid respectively.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05817780 |
| 出典データセット | uspto-grants-1998_10 |
| ORD ID | ord-384a7180a7be4d18a903534858b1c767 |
| 出典メモ | uspto-grants-1998_10 |