Toluene → 2,3,5-Triiodobenzoic acid
反応式
[CH:1]1[C:6]([I:7])=[C:5]([I:8])[C:4]([C:9]([OH:11])=[O:10])=[CH:3][C:2]=1[I:12].C1CCCCC1.C1(C)C=CC=CC=1>>[CH:1]1[C:6]([I:7])=[C:5]([I:8])[C:4]([C:9]([OH:11])=[O:10])=[CH:3][C:2]=1[I:12]参加物
3
実験手順
13.5 mL of TIBA/cyclohexane solution (113 g/L) were mixed with 3.2 mL of MAO/toluene solution (Albemarle 30% wt/wt, d=0.92 g/mL, 15.3 mmol MAO) to obtain a MAO/TIBA molar ratio of 2:1. The solution was stirred for 1 h at room temperature and transferred into a 50 mL Schlenk flask containing C-1 (28.4 mg, 38.3 μmol). The final solution was diluted with 7.7 mL of cyclohexane. Final mixture concentration=100 gTOT/L and 1.165 gmetallocene/L; color=dark red solution.
出典と根拠
- ORDレコード
- ord-abb03a218be545a394e304edce7838d6
- 出典データセット
- uspto-grants-2014_06
- 特許番号
- US08742042B2
反応ノート
読み込み中…