化工社化工社 化学情報印刷レポート · 研究参考用
2-Isopropylpyridine → 1-Oxo-2-(propan-2-yl)-1lambda~5~-pyridine
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 2-Isopropylpyridine | HCID 69523 | — |
| 反応物 | m-Chloroperbenzoic acid | HCID 70297 | — |
| 溶媒 | Dichloromethane | HCID 6344 | — |
| 生成物 | 1-Oxo-2-(propan-2-yl)-1lambda~5~-pyridine | HCID 13172079 | 85% |
反応手順
A mixture of isopropylpyridine (2.1 g, 17.75 mmol) and m-CPBA (5.0 g, 1.3 eq.) in CH2Cl2 was stirred overnight at room temperature. Then, the reaction mixture was diluted with CH2Cl2 (twice the volume) and successively washed with aqueous sodium bicarbonate (twice) and brine, dried (Na2SO4) and evaporated to give 2.0 g (85%) of the title compound 104.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US08741926B2 |
| 出典データセット | uspto-grants-2014_06 |
| ORD ID | ord-488d8dc885094e2fb161ff668d22dcab |
| 出典メモ | uspto-grants-2014_06 |