1,4-Dibromonaphthalene → 1,4-Bis(4-n-butylphenylethynyl)naphthalene

反応式

Br[C:2]1[C:11]2[C:6](=[CH:7][CH:8]=[CH:9][CH:10]=2)[C:5](Br)=[CH:4][CH:3]=1.[CH2:13]([C:17]1[CH:22]=[CH:21][C:20]([C:23]#[CH:24])=[CH:19][CH:18]=1)[CH2:14][CH2:15][CH3:16]>>[CH2:13]([C:17]1[CH:18]=[CH:19][C:20]([C:23]#[C:24][C:2]2[C:11]3[C:6](=[CH:7][CH:8]=[CH:9][CH:10]=3)[C:5]([C:24]#[C:23][C:20]3[CH:21]=[CH:22][C:17]([CH2:13][CH2:14][CH2:15][CH3:16])=[CH:18][CH:19]=3)=[CH:4][CH:3]=2)=[CH:21][CH:22]=1)[CH2:14][CH2:15][CH3:16]

参加物

反応物 2

HCID 665211,4-Dibromonaphthalene

HCID 27751321-Butyl-4-ethynylbenzene

生成物 1

HCID 867624721,4-Bis(4-n-butylphenylethynyl)naphthalene

実験手順

The title compound is prepared analogously to Example 3 from 1,4-dibromonaphthalene and two equivalents of 4-n-butylphenylacetylene.

出典と根拠

ORDレコード: ord-15cc48a10cc841d8ab8888e4acdd335b
出典データセット: uspto-grants-2014_06
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US08747695B2

反応ノート

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