化工社化工社 化学情報印刷レポート · 研究参考用
(3-Benzyloxy-phenoxy)-tert-butyl-dimethyl-silane → 3-(Tert-butyldimethylsilyl)oxy-1-cyclohexanol
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | (3-Benzyloxy-phenoxy)-tert-butyl-dimethyl-silane | HCID 58421755 | — |
| 溶媒 | Ethanol | HCID 702 | — |
| 生成物 | 3-(Tert-butyldimethylsilyl)oxy-1-cyclohexanol | HCID 557077 | — |
反応手順
A mixture of 37.6 g (3-benzyloxy-phenoxy)-tert-butyl-dimethyl-silane and 3.8 g of Nishimura's catalyst in 200 ml of ethanol was hydrogenated at rt under 50 psi for 6 hours. The reaction mixture was filtered and the filtrate concentrated.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US08754079B2 |
| 出典データセット | uspto-grants-2014_06 |
| ORD ID | ord-733f331f4f134e8484831a22c5f587cc |
| 出典メモ | uspto-grants-2014_06 |