Sodium Tetraphenylborate → 4-Azoniaspiro[3,4]octane tetraphenylborate

HRID 407280ノート

反応式

HRID 407280 の反応式
[C:1]1([B-:7]([C:20]2[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=2)([C:14]2[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=2)[C:8]2[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[Na+].[Cl-].[CH2:28]1[N+:31]2([CH2:35][CH2:34][CH2:33][CH2:32]2)[CH2:30][CH2:29]1>CC(C)=O>[C:20]1([B-:7]([C:1]2[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=2)([C:8]2[CH:9]=[CH:10][CH:11]=[CH:12][CH:13]=2)[C:14]2[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=2)[CH:21]=[CH:22][CH:23]=[CH:24][CH:25]=1.[CH2:30]1[N+:31]2([CH2:35][CH2:34][CH2:33][CH2:32]2)[CH2:28][CH2:29]1

参加物

4

反応物 2

HCID 2723787Sodium TetraphenylborateHCID 674420294-Azoniaspiro[3,4]octane chloride

生成物 1

HCID 866231814-Azoniaspiro[3,4]octane tetraphenylborate収率 90%

試薬・触媒・溶媒 1

HCID 180Acetone溶媒

実験手順

To a solution of sodium tetraphenylborate (1.90 g) in acetone (8 ml) at 20° C. was added aqueous 4-azoniaspiro[3,4]octane chloride (1.64 ml, prepared as above). The resulting solid was filtered, washed with water (3×10 ml) and dried in a vacuum oven to give 4-azoniaspiro[3,4]octane tetraphenylborate (2.17 g, 90% of theory).

後処理

  1. filtrationThe resulting solid was filtered
  2. washwashed with water (3×10 ml)
  3. customdried in a vacuum oven

出典と根拠

ORDレコード
ord-64edf62a941b4373b5be5956e534eea0
出典データセット
uspto-grants-2014_06
特許番号
US08754240B2

反応ノート

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