Formic Acid → N-(2-Chloro-6-(2-chloro-6-nitrophenylthio)phenyl) formamide

反応式

[Cl:1][C:2]1[CH:8]=[CH:7][CH:6]=[C:5]([S:9][C:10]2[C:15]([N+:16]([O-:18])=[O:17])=[CH:14][CH:13]=[CH:12][C:11]=2[Cl:19])[C:3]=1[NH2:4].[CH:20](O)=[O:21]>>[Cl:1][C:2]1[CH:8]=[CH:7][CH:6]=[C:5]([S:9][C:10]2[C:15]([N+:16]([O-:18])=[O:17])=[CH:14][CH:13]=[CH:12][C:11]=2[Cl:19])[C:3]=1[NH:4][CH:20]=[O:21]

参加物

反応物 2

HCID 284Formic Acid

HCID 682271432-Chloro-6-(2-chloro-6-nitrophenylthio)aniline

生成物 1

HCID 86670894N-(2-Chloro-6-(2-chloro-6-nitrophenylthio)phenyl) formamide

実験手順

A solution of 2-chloro-6-(2-chloro-6-nitrophenylthio)aniline (689 mg, 2.18 mmol) in formic acid (5 mL) was heated at reflux for 16 hours. The mixture was allowed to cool to room temperature and the solvent was evaporated. The residue was used without purification.

後処理

temperatureat reflux for 16 hours
customthe solvent was evaporated
customThe residue was used without purification

出典と根拠

ORDレコード: ord-109483b018414b45bc19ae2b0726448b
出典データセット: uspto-grants-2014_06
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US08759336B2

反応ノート

読み込み中…

参加物