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2,2'-Dimethyl-5,5'-bis(3-bromo-1-adamantyl)biphenyl → 2,2'-Dimethyl-5,5'-bis(3-(3,5-diethynylphenyl)-1-adamantyl)biphenyl
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 2,2'-Dimethyl-5,5'-bis(3-bromo-1-adamantyl)biphenyl | HCID 67524109 | — |
| 反応物 | 2,2'-Dimethyl-5,5'-bis(1-adamantyl)biphenyl | HCID 86641950 | — |
| 生成物 | 2,2'-Dimethyl-5,5'-bis(3-(3,5-diethynylphenyl)-1-adamantyl)biphenyl | HCID 86641951 | 73.5% |
反応手順
From the obtained 2,2′-dimethyl-5,5′-bis(1-adamantyl)-biphenyl 10 g, the same method as in Synthesis Example 7 was used to synthesize 2,2′-dimethyl-5,5′-bis(3-bromo-1-adamantyl)biphenyl 4.5 g, then the same method as in Synthesis Example 3 was used to obtain 2,2′-dimethyl-5,5′-bis(3-(3,5-diethynylphenyl)-1-adamantyl)biphenyl 3.8 g.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US08530596B2 |
| 出典データセット | uspto-grants-2013_09 |
| ORD ID | ord-8af8d5cfae954018b9b767f588c5e2c4 |
| 出典メモ | uspto-grants-2013_09 |