関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Dichloromethane | HCID 6344 | — |
| 反応物 | Methyl vinyl ketone | HCID 6570 | — |
| 反応物 | Chloroprene | HCID 31369 | — |
| 反応物 | Aluminum(III) Chloride | HCID 6451240 | — |
| 溶媒 | Water | HCID 962 | — |
| 生成物 | 1-Chloro-4-acetyl-cyclohexene | HCID 14365660 | — |
反応手順
To a solution of 98.1 parts of methyl vinyl ketone, 187 parts of anhydrous aluminum chloride and 1980 parts of methylene chloride was added 123 parts of chloroprene and the mixture was stirred at 25° C. for three hours and left standing for another 16 hours. Water was added to the reaction mixture and the organic layer was washed with 5% hydrochloric acid. Distillation gave a center cut of 61 parts of 1-chloro-4-acetyl-cyclohexene (125°-6° C./20 mm Hg). Reference: A. A. Petrov and N. P. Sopov, CA 42, 1910h (1948).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US04792618 |
|---|
| 出典データセット | uspto-grants-1988_12 |
|---|
| ORD ID | ord-19e3802694574392bda66521ea4de726 |
|---|
| 出典メモ | uspto-grants-1988_12 |
|---|
