化工社化工社 化学情報印刷レポート · 研究参考用
Dichloromethane → 4-Methyl-6-allyl-7-hydroxy-1-indanone
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Dichloromethane | HCID 6344 | — |
| 反応物 | Hexane | HCID 8058 | — |
| 反応物 | 4-Methyl-7-allyloxy-1-indanone | HCID 13604147 | — |
| 溶媒 | Tetralin | HCID 8404 | — |
| 生成物 | 4-Methyl-6-allyl-7-hydroxy-1-indanone | HCID 13604148 | — |
反応手順
32 Grams of 4-methyl-7-allyloxy-1-indanone was suspended in 100 ml of tetrahydronaphthalene. The suspension was refluxed by heating for 4 hours under argon gas atmosphere. The reaction mixture was subjected to a silica gel column chromatography (eluent: n-hexane, and dichloromethane: n-hexane=1:2) to obtain 26.8 g of 4-methyl-6-allyl-7-hydroxy-1-indanone.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04792628 |
| 出典データセット | uspto-grants-1988_12 |
| ORD ID | ord-ea059138b91c421798de0321bae6ec3f |
| 出典メモ | uspto-grants-1988_12 |