Hydrochloric Acid → 1,3,5-Tris-(p-(dodec-1-yloxycarbonyl)-anilino)-s-triazine

HRID 4159

反応式

HRID 4159 の反応式
[N:1]1[C:8](Cl)=[N:7][C:5](Cl)=[N:4][C:2]=1Cl.[NH2:10][C:11]1[CH:31]=[CH:30][C:14]([C:15]([O:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH3:29])=[O:16])=[CH:13][CH:12]=1.Cl>C1(C)C(C)=CC=CC=1>[CH2:18]([O:17][C:15]([C:14]1[CH:13]=[CH:12][C:11]([NH:10][N:1]2[CH2:8][N:7]([NH:10][C:11]3[CH:31]=[CH:30][C:14]([C:15]([O:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH3:29])=[O:16])=[CH:13][CH:12]=3)[CH2:5][N:4]([NH:10][C:11]3[CH:12]=[CH:13][C:14]([C:15]([O:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH3:29])=[O:16])=[CH:30][CH:31]=3)[CH2:2]2)=[CH:31][CH:30]=1)=[O:16])[CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH3:29]

参加物

5

反応物 3

HCID 313Hydrochloric AcidHCID 7954Cyanuric chlorideHCID 328885Dodecyl 4-aminobenzoate

生成物 1

HCID 201527391,3,5-Tris-(p-(dodec-1-yloxycarbonyl)-anilino)-s-triazine

試薬・触媒・溶媒 1

HCID 7237O-Xylene溶媒

反応条件

温度
80 °C

実験手順

18.5 g of cyanuric chloride and 92 g of dodecyl p-aminobenzoate in 1,000 ml of xylene were heated at 140° C. until HCl gas was no longer evolved. After 8 hours, the reaction solution was cooled to 80° C., washed twice with saturated sodium bicarbonate solution and once with water, and then cooled to room temperature. The precipitated crystals were filtered off under suction and dried.

後処理

  1. washwashed twice with saturated sodium bicarbonate solution and once with water
  2. temperaturecooled to room temperature
  3. filtrationThe precipitated crystals were filtered off under suction
  4. customdried

出典と根拠

ORDレコード
ord-6b8bf34c051a47799634f0478cd59831
出典データセット
uspto-grants-1988_02
特許番号
US04724137

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