化工社化工社 化学情報印刷レポート · 研究参考用
2-Methylfuran → 1-Methyl-10-oxa-tricyclo[5.2.1.0*2,6*]dec-8-ene-3,5-dione
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 2-Methylfuran | HCID 10797 | — |
| 反応物 | 2-Cyclopentene-1,4-dione | HCID 70258 | — |
| 溶媒 | Methanol | HCID 887 | — |
| 生成物 | 1-Methyl-10-oxa-tricyclo[5.2.1.0*2,6*]dec-8-ene-3,5-dione | HCID 58288601 | — |
反応手順
A mixture of 4-cyclopentene-1,3-dione (10 g, 104 mmol) and 2-methylfuran (15 ml) are stirred at room temperature for 3 days. Methanol (50 ml) is then added and the solid is collected and dried on a Buchner funnel to give 1-methyl-10-oxa-tricyclo[5.2.1.0*2,6*]dec-8-ene-3,5-dione (14.3 g)
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US08530667B2 |
| 出典データセット | uspto-grants-2013_09 |
| ORD ID | ord-31f574acb1d14478b81e748c79a80f90 |
| 出典メモ | uspto-grants-2013_09 |