Triethyloxonium tetrafluoroborate → 1-Butylpyridinium Tetrafluoroborate

HRID 423137ノート

反応式

HRID 423137 の反応式
[F:1][B-:2]([F:5])([F:4])[F:3].C([O+](CC)CC)C.[Br-].[CH2:14]([N+:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1)[CH2:15][CH2:16][CH3:17]>ClCCl>[F:1][B-:2]([F:5])([F:4])[F:3].[CH2:14]([N+:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1)[CH2:15][CH2:16][CH3:17]

参加物

4

反応物 2

HCID 2723982Triethyloxonium tetrafluoroborateHCID 27342381-Butylpyridinium bromide

生成物 1

HCID 27341801-Butylpyridinium Tetrafluoroborate収率 98.6%

試薬・触媒・溶媒 1

HCID 6344Dichloromethane溶媒

実験手順

2.48 g (13.04 mmol) of triethyloxonium tetrafluoroborate are added to a solution of 2.77 g (12.82 mmol) of 1-butylpyridinium bromide in 10 ml of dry dichloromethane. The reaction mixture is stirred at room temperature for 30 minutes. All volatile products are subsequently removed over the course of 30 minutes in a vacuum of 13.3 Pa and at 80° C. (oil-bath temperature), giving 2.82 g of 1-butylpyridinium tetrafluoroborate as liquid. The yield is approximately quantitative.

後処理

  1. customAll volatile products are subsequently removed over the course of 30 minutes in a vacuum of 13.3 Pa and at 80° C. (oil-bath temperature)

出典と根拠

ORDレコード
ord-df4449927a634a0eaba00ceffebdd336
出典データセット
uspto-grants-2012_01
特許番号
US08101749B2

反応ノート

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