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Triphenylphosphine → 2-(4-Bromophenoxy)propyl 2-methylacrylate
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Triphenylphosphine | HCID 11776 | — |
| 反応物 | 2-Hydroxypropyl methacrylate | HCID 13539 | — |
| 反応物 | 2-Bromo-1,4-benzenediol | HCID 68502 | — |
| 反応物 | Diisopropyl azodicarboxylate | HCID 5363146 | — |
| 溶媒 | Tetrahydrofuran | HCID 8028 | — |
| 生成物 | 2-(4-Bromophenoxy)propyl 2-methylacrylate | HCID 59005016 | — |
反応手順
Following the same preparation procedure of Example 2, the reaction was carried out with 4-hydroxy bromophenol (4 g), 2-hydroxypropyl 2-methylacrylate (3.33 g), triphenyl phosphine (6.06 g) and DIAD (4.69 g) in 50 ml of THF to give after chromatography purification pure 2-(4-bromophenoxy)propyl 2-methylacrylate as pale yellow oil.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US08105662B2 |
| 出典データセット | uspto-grants-2012_01 |
| ORD ID | ord-50bf399bb55646d6837673bbf30e7dea |
| 出典メモ | uspto-grants-2012_01 |