Dibromonaphthalic anhydride → Naphthalic anhydride

HRID 425134

反応式

HRID 425134 の反応式
BrC1C(Br)=C([C:12]([O:14][C:15]([C:17]2[C:26]3[C:21](=[CH:22][CH:23]=[CH:24][CH:25]=3)[CH:20]=[C:19](Br)[C:18]=2Br)=[O:16])=[O:13])C2C(C=1)=CC=CC=2>CCOCC>[CH:23]1[CH:22]=[C:21]2[C:26]3=[C:25]([C:12]([O:14][C:15](=[O:16])[C:17]3=[CH:18][CH:19]=[CH:20]2)=[O:13])[CH:24]=1

参加物

3

反応物 1

HCID 87118624Dibromonaphthalic anhydride

生成物 1

HCID 6693Naphthalic anhydride

試薬・触媒・溶媒 1

HCID 3283Diethyl Ether溶媒

実験手順

The following morning thin-layer chromatography showed only a trace presence of the dibromonaphthalic anhydride. The reaction mixture was cooled to room temperature followed by the addition of 350 ml of ether. The triethylamine hydrobromide byproduct was removed by filtration. The filtrate was concentrated on the rotary evaporator, to give the diphenylethynyl derivative of the 1,8-naphthalic anhydride.

後処理

  1. customThe triethylamine hydrobromide byproduct was removed by filtration
  2. concentrationThe filtrate was concentrated on the rotary evaporator

出典と根拠

ORDレコード
ord-a4c31501d93647848a5dd956a975d0b9
出典データセット
uspto-grants-2012_01
特許番号
US08106142B2

関連ノート

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