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Oxalyl chloride → 2-Furansulfonyl isocyanate
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Oxalyl chloride | HCID 65578 | — |
| 反応物 | Diazabicyclo(2.2.2)octane | HCID 136165 | — |
| 反応物 | Furan-2-sulfonamide | HCID 13668256 | — |
| 溶媒 | Toluene | HCID 1140 | — |
| 生成物 | 2-Furansulfonyl isocyanate | HCID 23342478 | — |
反応手順
Dry toluene (150 ml), 25 ml oxalyl chloride (295), and a trace of DABCO (diaza-bicyclo[2.2.2]octane) were heated to 90°. Ten g of 2-furansulfonamide was added over a 15 minute period and the mixture was held at 95° for 2 hours. After filtering, the solvent was removed under vacuum to yield 2.1 g of an oil showing the characteristic isocyanate absorption in the infrared (2280 cm-1).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04169719 |
| 出典データセット | uspto-grants-1979_10 |
| ORD ID | ord-e461e0af470f4738aede9d41910ec5f4 |
| 出典メモ | uspto-grants-1979_10 |